Generalized Local Density Approximation Uniform Electron Gases . II . The Generalized Local Density Approximation in One Dimension
نویسندگان
چکیده
We introduce a generalization (gLDA) of the traditional Local Density Approximation (LDA) within density functional theory. The gLDA uses both the one-electron Seitz radius rs and a two-electron hole curvature parameter η at each point in space. The gLDA reduces to the LDA when applied to the infinite homogeneous electron gas but, unlike the LDA, is is also exact for finite uniform electron gases on spheres. We present an explicit gLDA functional for the correlation energy of electrons that are confined to a one-dimensional space and compare its accuracy with LDA, secondand third-order Møller-Plesset perturbation energies and exact calculations for a variety of inhomogeneous systems.
منابع مشابه
Uniform electron gases. II. The generalized local density approximation in one dimension.
We introduce a generalization (gLDA) of the traditional Local Density Approximation (LDA) within density functional theory. The gLDA uses both the one-electron Seitz radius rs and a two-electron hole curvature parameter η at each point in space. The gLDA reduces to the LDA when applied to the infinite homogeneous electron gas but, unlike the LDA, it is also exact for finite uniform electron gas...
متن کاملPii: S0166-1280(99)00412-1
Local exchange-correlation functionals are defined for different systems with spherical symmetry, by requiring that they reproduce the correct exchange-correlation energy and exchange-correlation potential (up to a constant). For comparison, the results with the uniform electron gas local density approximation and a generalized gradient approximation are also shown. q 2000 Elsevier Science B.V....
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